Chloride Attack!

What are chlorides and why are they so detrimental to concrete?

The chloride attack mechanism – deterioration by stealth!

Chlorides are reactive chemicals that enter concrete through the constant movement of moisture in and out of the capillary pores. Chlorides, together with oxygen, reach the embedded steel and initiate electrochemical corrosion of the rebar. Untreated steel corrosion will very often cause the concrete to break down well short of its planned service life.

How chlorides and other contaminants attack concrete reinforcing steel

Chlorides are typically present in seawater, putting marine structures at particular risk. Other sources include salt-contaminated groundwater or de-icing salts.

All concrete structures in marine environments are under threat from chloride attack. Spray-applied hydrogel treatment is being used for protection of this Lincolnshire seawall.
All concrete structures in marine environments are at risk of chloride attack. Spray-applied hydrogel treatment is being used for the protection of this Lincolnshire seawall.

How can we halt the process?

It is a proven fact that controlling free moisture will significantly extend concrete life. This is because moisture is the vehicle by which contaminants enter and move through the concrete.

Chloride ingress and corrosion activity can be prevented by providing a penetrating moisture barrier. This moisture barrier must be long-lasting and effective. A coating is not sufficient; moisture must be immobilised within the concrete itself to prevent the movement and action of the moisture-borne contaminants.

Chloride attack works inside the concrete. Once obvious cracking develops, the deterioration is well advanced.

What is an effective way to control moisture from inside and out?

You need a concrete treatment system that:

  • penetrates the pores of the concrete,
  • deals with the moisture currently in the concrete, and
  • blocks the entrance of outside moisture.

In fact, you need a penetrating hydrogel treatment.

Penetrating hydrogel

How does it work?

  1. A catalytic silicate solution is applied to the concrete by spray or admixture.
  2. The catalyst reacts with the free lime (CaOH) in the concrete.
  3. This hydrophilic reaction draws in the concrete’s moisture (H2O) content, penetrating deep into the porosity.
  4. The result is calcium-silicate-hydrate (C-S-H) gel.
  5. The hydrogel maintains moisture in the concrete, aiding the entire hydration process.
Penetrating hydrogel treatment is permanent, highly effective, and safe for the environment.

Intrigued?

Looking after a deteriorating concrete structure? Get in touch!


For more on this topic, try our on-demand webinar, “The Marine Concrete Experience“.

Scroll to Top